武汉理工大学纳米重点实验室

李琪，副研究员

武汉理工大学

先进能源科学与技术广东省实验室佛山仙湖实验室

Email: qi.li@whut.edu.cn

 Tel: 134 7686 5921

教育经历

2003 － 2007，墨尔本大学化工系，博士，导师：Prof. Frank Caruso

1999 － 2002，北京大学化学与分子工程学院，硕士，高分子化学与物理

导师：曹维孝 教授

1995 － 1999，北京大学化学与分子工程学院，学士

研究工作经历

2020.6 – 至今 先进能源科学与技术广东省实验室佛山仙湖实验室，副研究员

2016.11 – 至今 武汉理工大学材料复合与新技术国家重点实验室，副研究员

2016.5 – 2016.11 武汉理工大学材料复合与新技术国家重点实验室，助理研究员

2007 - 2012  莫纳什大学，博士后，合作导师：Prof. Alan Bond

研究方向

本人长期从事纳米材料的可控制备与应用的研究工作，近年来主要研究兴趣在电化学能源存储与转换，以应用为导向开展创新性的研究工作，致力于为能源存储与转换体系走向产业化面临的关键科学问题做深入探究并提供解决方案。在柔性储能方面，期望结合先进的打印技术，实现高性能、低成本、安全稳定的柔性储能器件，目标在与柔性光伏、柔性传感等柔性电子器件整合，为人们的生活提供便利。近年来，本人在纳米能源材料的可控制备、结构调控、化学/电化学反应机制等方面取得了一系列创新性的研究成果，在 Adv. Mater., Adv. Energy Mater., Adv. Funct. Mater., Angew. Chem. Int. Ed., Nano Lett., Nano Energy等国际知名期刊发表SCI论文近60篇，其中第一作者或通讯作者论文31篇。Energy Environ. Sci., Adv. Energy Mater., Angew. Chem.等国际知名期刊的邀请审稿人，主持国家自然科学基金1项。

研究课题以纳米能源材料，尤其是以金属-有机配位聚合物材料的可控制备与结构调控为核心，开发高效电极材料及聚合物凝胶电解质，应用于高性能、长循环的水系、非水系准固态电池体系。结合材料的可控热解，设计制备结构可控的金属单原子催化剂，用于高效电催化反应。并期望结合先进表征技术与理论计算，揭示其电化学反应机制。

代表性论文

1.     Wen, B.; Guo, R.; Liu, X.; Luo, W.; He, Q.; Niu, C.; Meng, J.; Li, Q.*; Zhao, Y.; Mai, L., Niobium oxyphosphate nanosheet assembled two-dimensional anode material for enhanced lithium storage. J. Energy Chem. 2021, 53, 268-275.

2.     Hu, Z.; He, Q.; Liu, Z.; Liu, X.; Qin, M.; Wen, B.; Shi, W.; Zhao, Y.; Li, Q.*; Mai, L.*, Facile formation of tetragonal-Nb₂O₅ microspheres for high-rate and stable lithium storage with high areal capacity. Sci. Bull. 2020, 65 (14), 1154-1162. (cover article)

3.     Liu, F.; Liu, S.; Meng, J.; Xia, F.; Xiao, Z.; Liu, Z.; Li, Q.*; Wu, J.*; Mai, L., Stabilizing conversion reaction electrodes by MOF derived N-doped carbon shell for highly reversible lithium storage. Nano Energy 2020, 73. 104758

4.     Shi, W.; Meng, J.; Li, Q.*; Xiao, Z.; Xu, X.; Qin, M.; Zhang, X.; Mai, L., Ternary TiO₂/SiO_x@C nanocomposite derived from a novel titanium-silicon MOF for high-capacity and stable lithium storage. Chem. Comm. 2020, 56 (18), 2751-2754.

5.     Wang, Y.; Hong, X.; Guo, Y.; Zhao, Y.; Liao, X.; Liu, X.; Li, Q.; He, L.*; Mai, L.*, Wearable Textile-Based Co-Zn Alkaline Microbattery with High Energy Density and Excellent Reliability. Small 2020, 16 (16), e2000293.

6.     Li, M.; He, Q.; Li, Z.; Li, Q.*; Zhang, Y.; Meng, J.; Liu, X.; Li, S.; Wu, B.; Chen, L.; Liu, Z.; Luo, W.; Han, C.*; Mai, L.*, A Novel Dendrite-Free Mn²⁺/Zn²⁺ Hybrid Battery with 2.3 V Voltage Window and 11000-Cycle Lifespan. Adv. Energy Mater. 2019, 1901469.

7.     Huang, M.; Li, M.; Niu, C.; Li, Q.*; Mai, L.*, Recent Advances in Rational Electrode Designs for High-Performance Alkaline Rechargeable Batteries. Adv. Funct. Mater. 2019, 29 (11), 1807847.

8.     Liu, X.; Ni, K.; Wen, B.; Guo, R.; Niu, C.; Meng, J.; Li, Q.; Wu, P.; Zhu, Y.; Wu, X.*; Mai, L.*, Deep Reconstruction of Nickel-Based Precatalysts for Water Oxidation Catalysis. ACS Energy Lett. 2019, 4 (11), 2585-2592.

9.     Qin, M.; Ren, W.; Meng, J.; Wang, X.; Yao, X.; Ke, Y.; Li, Q.*; Mai, L., Realizing Superior Prussian Blue Positive Electrode for Potassium Storage via Ultrathin Nanosheet Assembly. ACS Sus. Chem. & Eng. 2019, 7 (13), 11564-11570.

10.  Ren, W.; Zhu, Z.; Qin, M.; Chen, S.; Yao, X.; Li, Q.*; Xu, X.; Wei, Q.; Mai, L.*; Zhao, C.*, Prussian White Hierarchical Nanotubes with Surface-Controlled Charge Storage for Sodium-Ion Batteries. Adv. Funct. Mater. 2019, 29 (15), 1806405.

11.  Liu, X.; Ni, K.; Niu, C.; Guo, R.; Xi, W.*; Wang, Z.; Meng, J.; Li, J.; Zhu, Y.; Wu, P.; Li, Q.; Luo, J.; Wu, X.*; Mai, L.*, Upraising the O 2p Orbital by Integrating Ni with MoO₂ for Accelerating Hydrogen Evolution Kinetics. ACS Catalysis 2019, 9 (3), 2275-2285.

12.  Guo, Y.; Hong, X.; Wang, Y.; Li, Q.; Meng, J.; Dai, R.; Liu, X.; He, L.*; Mai, L.*, Multicomponent Hierarchical Cu-Doped NiCo-LDH/CuO Double Arrays for Ultralong-Life Hybrid Fiber Supercapacitor. Adv. Funct. Mater. 2019, 29 (24), 1809004.

13.  Liu, D.; Xu, X.; Tan, J.; Zhu, J.; Li, Q.*; Luo, Y.; Wu, P.; Zhang, X.; Han, C.; Mai, L.*, Micrometer-Sized Porous Fe₂N/C Bulk for High-Areal-Capacity and Stable Lithium Storage. Small 2019, 15 (2), 1803572.

14.  Yao, X. H.; Ke, Y. J.; Ren, W. H.; Wang, X. P.; Xiong, F. Y.; Yang, W.; Qin, M. S.; Li, Q.*; Mai, L. Q.*; Defect-Rich Soft Carbon Porous Nanosheets for Fast and High-Capacity Sodium-Ion Storage, Adv. Energy Mater., 2018, 1803260. (highly cited paper from Web of Science)

15.  Li, M.; Meng, J. S.; Li, Q.*; Huang, M.; Liu, X.; Owusu, K. A.; Liu, Z. A.; Mai, L. Q.*; Finely Crafted 3D Electrodes for Dendrite‐Free and High‐Performance Flexible Fiber‐Shaped Zn–Co Batteries, Adv. Funct. Mater., 2018, 1802016.

16.  Xiao, Z. T.; Meng, J. S.; Li, Q.*; Zhang X.; Liu, Z. A.; Wen, B.; Han, C. H.; Mai, L. Q.*; General and precise carbon confinement of functional nanostructures derived from assembled metal-phenolic network for enhanced lithium storage, J. Mater. Chem. A, 2018, 6 (38), 18605 (2018 Journal of Materials Chemistry A HOT Papers)

17.  Li, Q.*; Hu, Z. Q.; Liu, Z. A.; Zhao, Y. L.; Li, M.; Meng, J. S.; Tian, X. C.; Xu, X. M.; Mai, L. Q.*; Recent advances in nanowire-based flexible freestanding electrodes for energy storage, Chem. Eur. J., 2018, 24 (69), 18307 (Frontispiece Review Showcase)

18.  Xu, X. M.; Wu, P. J.; Li, Q.*; Yang, W.; Zhang, X.; Wang, X. P.; Meng, J. S.; Niu, C. J.; Mai, L. Q.*; Realizing stable lithium and sodium storage with high areal capacity using novel nanosheet-assembled compact CaV₄O₉ microflowers, Nano Energy, 2018, 50, 606.

19.  Liu, X.; Wen, B.; Guo, R. T.; Meng, J. S.; Liu, Z. A.; Yang, W.; Niu, C. J.; Li Q.*; Mai, L. Q.*; A porous nickel cyclotetraphosphate nanosheet as a new acid-stable electrocatalyst for efficient hydrogen evolution, Nanoscale, 2018, 10, 9856.

20.  Wang, X.; Han, K.; Wang, C.; Liu, Z.; Xu, X.; Huang, M.; Hu, P.; Meng, J.; Li, Q.*; Mai, L.*, Graphene oxide-wrapped dipotassium terephthalate hollow microrods for enhanced potassium storage. Chem. Comm. 2018, 54 (78), 11029-11032.

21.  Liu, X.; Ni, K.; Wen, B.; Niu, C.; Meng, J. S.; Guo, R. T.; Li, Q.; Li, J. T.; Zhu, Y.; W, X. J. Zhao, D. Y.; Mai, L. Q.*; Polyoxomolybdate-derived carbon-encapsulated multicomponent electrocatalysts for synergistically boosting hydrogen evolution, J. Mater. Chem. A, 2018, 6 (37), 17874

22.  Ren, W. H.; Liu, D. N.; Sun, C. L.; Yao, X. H.; Tan, J.; Wang, C. M.; Zhao, K. N.; Wang, X. P.; Li, Q.*; Mai, L. Q.*; Nonhierarchical Heterostructured Fe₂O₃/Mn₂O₃ Porous Hollow Spheres for Enhanced Lithium Storage Small, 2018, 14, 1800659

23.  Zhang, Y. J.; Meng, J. S.; Wang, X. P.; Liu, X.; Xu, X. M.; Liu, Z. A.; Owusu, K. A.; Huang, C. Y.; Li, Q.*; Mai, L. Q.*; Stepwise Chelation-Etching Synthesis of Carbon-Confined Ultrafine SnO₂ Nanoparticles for Stable Sodium Storage, Chem. Comm., 2018, 54, 1469.

24.  Han, C. H.*; Han, K.; Wang, X. P.; Wang, C. Y.; Li, Q.; Meng, J. S.; Xu, X. M.; He, Q.; Luo, W.; Wu, L. M.; Mai, L. Q.*; Three-Dimensional Carbon Network Confined Antimony Nanoparticles Anode for High-Capacity K-Ion Batteries, Nanoscale, 2018, 10, 6820 (highly cited paper from Web of Science)

25.  Ren, W. H.; Qin, M. S.; Zhu, Z. X.; Yan, M. Y.; Li, Q.*; Zhang, L.; Liu, D. N.; Mai, L. Q.*; Activation of Sodium Storage Sites in Prussian Blue Analogues via Surface Etching, Nano Lett., 2017, 17, 4713.

26.  Meng, J. S.; Niu, C. J.; Xu, L. H.; Li, J. T.; Liu, X.; Wang, X. P.; Wu, Y. Z.; Xu, X. M.; Chen, W. Y.; Li, Q.; Zhu, Z. Z.*; Zhao, D. Y.; Mai, L. Q.*; General Oriented Formation of Carbon Nanotubes from Metal− Organic Frameworks, J. Am. Chem. Soc., 2017, 139, 8212 (highly cited paper from Web of Science)

27.  Wu, Y.Z.; Meng, J.S.; Li, Q.*; Niu, C.J.; Wang, X.P.; Yang, W.; Li, W.; Mai, L.Q.*; Interface-modulated fabrication of hierarchical yolk-shell Co₃O₄/C dodecahedrons as stable anodes for lithium and sodium storages, Nano Res., 2017, DOI 10.1007/s12274-017-1433-6

28.  He, Q.; Liu, J. S.; Li, Z. H.; Li, Q.*; Xu, L.; Zhang, B. X.; Meng, J. S.; Wu, Y. Z.; Mai, L. Q.*; Solvent-Free Synthesis of Uniform MOF Shell-Derived Carbon Confined SnO₂/Co Nanocubes for Highly Reversible Lithium Storage, Small, 2017, 1701504.

29.  Wang, X. P.; Han, K.; Qin, D. D.; Li, Q.*; Wang, C. Y.; Niu, C. J.; Mai, L. Q.*; Polycrystalline soft carbon semi-hollow microrod anode for advanced K-ion full batteries, Nanoscale, 2017, 9, 18216.

30.  Meng, J. S.; Liu, X. ; Li, J. T.; Li, Q.; Zhao, C.; Xu, L. H.; Wang, X. P.; Liu, F.; Yang, W.; Xu, X. M.; Liu, Z.; Niu, C. J.*; Mai, L. Q.*; General Oriented Synthesis of Precise Carbon-Confined Nanostructures by Low-Pressure Vapor Superassembly and Controlled Pyrolysis, Nano Lett., 2017, 17, 7773

31.  Meng, J. S.; Guo, H. C.; Niu, C. J.; Zhao, Y. L.; Xu, L.*; Li, Q.; Mai, L. Q.*; Advances in Structure and Property Optimizations of Battery Electrode Materials, Joule, 2017, 08, 001. (highly cited paper from Web of Science)

32.  Liu, Z. A.; Guo, R. T.; Meng, J. S.; Liu, X.; Wang, X. P.; Li, Q.*; Mai, L. Q.*; Facile electrospinning formation of carbon-confined metal oxide cube-in-tube nanostructures for stable lithium storage, Chem. Comm., 2017, 53, 8284.

33.  Adeel, S.; Abdelhamid, M. E.; Nafady, A.; Li, Q.; Martin, L. L.*; Bond, A. M.*; Voltammetric studies on the inter-relationship between the redox chemistry of TTF, TTF⁺, TTF²⁺ and HTTF⁺ in acidic media, RSC Advances, 2015, 5, 18384

34.  Li, Q.; Lu, J.; Boas, J. F.; Traore, D. A. K.; Wilce, M. C. J.; Martin, L. L.*; Ueda, T.; Bond, A. M.*; Spontaneous Redox Synthesis and Characterization of the Tetrathiafulvalene-Vanadium-Substituted Polyoxometalate Charge-Transfer Material TTF₄[SVW₁₁O₄₀]: Comparison with the Mo Analogue, Inorg. Chem., 2014, 53, 10996.

35.  Adeel, S. M.; Li, Q.; Nafady, A.; Zhao, C.; Siriwardana, A. I.; Bond, A. M.*; Martin, L. L.*; A systematic study of the variation of tetrathiafulvalene (TTF), TTF^+• and TTF²⁺ reaction pathways with water in the presence and absence of light, RSC Advances, 2014, 4, 49789.

36.  Huang, F.; Chen, D.; Li, Q.; Caruso, R. A.*; Cheng, Y.-B.*, Construction of nanostructured electrodes on flexible substrates using pre-treated building blocks. Appl. Phys. Lett. 2012, 100 (12), 123102.

37.  Huang, F.; Li, Q.; Thorogood, G. J.; Cheng, Y.-B.*; Caruso, R. A.*, Zn-doped TiO₂ electrodes in dye-sensitized solar cells for enhanced photocurrent. J. Mater. Chem. 2012, 22 (33), 17128-17132.

38.  Li, Q.; Lu, J. Z.; Boas, J. F.; Traore, D. A. K.; Wilce, M. C. J.; Huang, F. Z.; Martin, L. L.*; Ueda, T.; Bond A. M.*; Spontaneous Redox Synthesis of the Charge Transfer Material TTF₄[SVMo₁₁O₄₀], Inorg. Chem., 2012, 51, 12929.

39.  Li, Q.; Zhao, C.; Bond, A. M.*; Boas, J. F.; Moubaraki, B and Murray, K. S.; Wedd, A. G.*; Controlled potential electrodeposition of a microcrystalline thin film of the charge transfer material tetrathiafulvalene-polyoxometalate of approximate composition (TTF)(5.3)(Bu₄N)(0.7)[P₂W₁₈O₆₂]• 3H₂O,  J. Mater. Chem., 2011, 21, 5398.

40.  Connal, L. A.; Li, Q.; Quinn, J. F.; Tjipto, E.; Caruso, F*; Qiao, G. G.*; PH-responsive poly(acrylic acid) core cross-linked star polymers: Morphology transitions in solution and multilayer thin films, Macromolecules, 2008, 41, 2620.

41.  Zelikin, A. N.; Li, Q.; Caruso, F.*; Disulfide-stabilized poly(methacrylic acid) capsules: Formation, cross-linking, and degradation behavior, Chem. Mater., 2008, 20, 2655

42.  Zelikin, A. N.; Li, Q.; Caruso, F.*; Degradable Polyelectrolyte Capsules Filled with Oligonucleotide Sequences, Angew. Chem. Int. Ed., 2006, 45, 7743.

43.  Li, Q.; Quinn, J. F.; Caruso, F.*; Nanoporous Polymer Thin Films via Polyelectrolyte Templating, Adv. Mater., 2005, 17, 2058.

44.  Li, Q.; Quinn, J. F.; Wang, Y. J.; Caruso, F.*; Preparation of Nanoporous Polyelectrolyte Multilayer Films via Nanoparticle Templating, Chem. Mater., 2006, 18, 5480.

45.  Li, Q.; Ouyang, J. H.; Chen, J. Y.; Zhao, X. S.; Cao, W. X.*, Photosensitive, self-assembled ultrathin films based on diazoresin and phosphate-containing polyanions. J. Polym. Sci. Polym. Chem. 2002, 40 (2), 222-228.

46.  Li, Q.; Chen, J. Y.; Li, Z. C.; Cao, W. X.*, Diazoresin-polyphosphoric acid complex. Acta Polym. Sin. 2001, 1, 134

发明专利

(1) 中国专利, 李琪; 郭瑞婷; 麦立强; 刘熊; 王选朋, 介孔碳纳米线及其制备和应用, 申请号CN201910703050.9

(2) 中国专利, 李琪; 覃明盛; 麦立强; 王选朋, 普鲁士蓝纳米花电极材料及其制备方法与应用, 申请号CN201910103458.2

(3) 中国专利, 韩春华; 李明; 麦立强; 李琪, 柔性自支撑一体化MnO₂柔性电极及其制备方法和应用, 申请号CN201910350572.5

主要科研项目

（1）国家自然科学基金青年基金，2019-2021，25.2万元，负责

（2）武汉理工大学海外人才引进科研启动项目，2016-2018，40万元，负责